doi: 10.52899/24141437_2025_01_115
UDK: 621.791.92
Diffusion-kinetic model of intermetallidic phase development and growth in three-component Ni-based solid solutions based on diffusion coefficient temperature dependence
Коваленко Е. К.,
Валдайцева Е. А.,
Туричин Г. А.
Article language: English
Citation Link: Kovalenko EK, Valdaytseva EA, Turichin GA. Diffusion-kinetic model of intermetallidic phase development and growth in three component Ni-based solid solutions based on diffusion coefficient temperature dependence. Transactions of the Saint Petersburg State Marine Technical University. 2025;4(1):115–122.
DOI: https://doi.org/10.52899/24141437_2025_01_115
Annotation
BACKGROUND: Nickel alloys are used in various industries due to their attractive mechanical properties. Nickel alloys are
also widely used in additive manufacturing to make complex-shaped products. The direct laser deposition method implies high
heating and cooling rates, which can be influenced by manufacturing parameters such as laser power and manufacture speed.
AIM: A diffusion-kinetic model will allow to make calculations of the size of the intermetallidic phase in various direct laser
deposition modes in Ni alloys.
MATERIALS AND METHODS: This article describes a model for calculating the sizes of the intermetallidic phase in a threecomponent
Ni alloy in a chemical reaction between the alloying elements only.
RESULTS: Calculation of the size of the intermetallidic phase will allow to forecast the mechanical properties of products
manufactured by direct laser deposition before the actual manufacture. A next step is to validate this diffusion-kinetic model
subject to the chemical reaction between the alloying elements only.
CONCLUSIONS: The paper presents a model used to calculate the size of intermetallic phase made of alloying elements in
a three-component nickel alloy. The model will help to predict the size of intermetallic compounds and, thus, the mechanical
properties of products.
Keywords: diffusion-kinetic model; three-component Ni alloys; calculation of inclusions size; direct laser deposit; additive manufacturing techniques.
Bibliography
1. Jinoop AN, Paul CP, Bindra KS. Laser-assisted directed energy deposition of nickel super alloys: a review. Proc Inst Mech Eng Pt L J Mater Des Appl. 2019;233(11):2376–2400. doi: 10.1177/1464420719852658
2. Alves Ferreira A, Loureiro Amaral R, Correia Romio P, et al. Deposition of nickel-based superalloy claddings on low alloy structural steel by direct laser deposition. Metals. 2021;11(8):1326. doi: 10.3390/met11081326
3. Conduit BD, Illston T, Baker S, et al. Probabilistic neural network identification of an alloy for direct laser deposition. Mater Des. 2019;168:107644. doi: 10.1016/j.matdes.2019.107644
4. Alves Ferreira A, Loureiro Amaral R, Correia Romio P, et al. Deposition of nickel-based superalloy claddings on low alloy structural steel by direct laser deposition. Metals. 2021;11(8):1326. doi: 10.3390/met11081326
5. Alekseev AV, Valdaytseva EA, Aleksandrov VL. Modeling of the formation process of the coherent intermetallides in nickel alloys during laser treatment. Key Eng Mater. 2019;822:438–444. doi: 10.4028/www.scientific.net/KEM.822.438
6. Alekseev AV, Turichin GA, Klimova-Korsmik OG, et al. Simulation of the Ni3Al intermetallic inclusion growth process during direct laser deposition using Ni-based superalloy powder. Materials Today: Proceedings. 2020;30-3:756–760. doi: 10.1016/j.matpr.2020.01.562
7. Lopota V, Turichin G, Valdaitseva E, et al. Theoretical investigation and modelling of intermetallic inclusions formation in laser treatment of Al-Mg alloys. SPIE Proc. 2004;5399. doi: 10.1117/12.555548
8. Prokhorov NN. Physical processes in metals at welding. Vol. 1. Moscow: Metallurgy; 1976. 695 p. (In Russ.)
9. Frank-Kamenetsky DA. Fundamentals of macrokinetics. Diffusion and heat transfer in chemical kinetics: Textbookmonograph. 4th ed. Dolgoprudny: Intellect Publishing House; 2008. 408 p. (In Russ.)